Recovery Koagulan dari Sludge WWTP Pembangkit Listrik Tenaga Uap sebagai Alternatif Pengolahan Air Limbah secara Kimia

Adhi Setiawan, Ahmad Erlan Afiuddin, Qurrotul Aini, Tanti Utami Dewi

Abstract


Proses koagulasi di wastewater treatment plant (WWTP) menghasilkan produk samping berupa limbah lumpur atau sludge dalam jumlah besar serta belum dimanfaatkan secara optimal. Penelitian ini bertujuan untuk melakukan karakterisasi terhadap sludge, menganalisis pengaruh konsentrasi asam klorida pada proses recoveri koagulan, serta menganalisis pengaruh dosis koagulan hasil recovery sludge terhadap removal TSS, Zn, dan Fe. Metode karakterisasi sludge menggunakan SEM-EDX, XRD, dan FTIR. Proses recovery koagulan menggunakan metode pengasaman dengan menggunakan HCl pada konsentrasi 1 N hingga 3 N. Hasil penelitian menunjukkan bahwa sludge memilki kandungan Fe sebesar 69,29% wt dalam bentuk Fe(OH)3 dan Fe2O3. Konsentrasi pengasaman dengan HCl 3N menghasilkan SRP dengan kandungan koagulan Fe yang tertinggi yakni sebesar 52,3 mg/L.  Hasil jar tes menunjukkan bahwa penambahan SRP 3 N pada dosis 10 mL/L menghasilkan konsentrasi residual TSS dan Zn paling rendah yakni sebesar 34 mg/L dan 0,01 mg/L.  Besarnya persen removal TSS dan Zn pada SRP 3N dengan dosis 10 mL/L masing-masing sebesar 79,4% dan 9,52%. Namun, removal Fe tertinggi pada SRP 1 N dengan dosis 4 mL/L. Jenis dan dosis SRP yang direkomendasikan untuk menurunkan TSS, Fe, dan Zn antara lain SRP 1 N dengan semua  dosis  yaitu  4  mL/L,  6  mL/L,  8  mL/L,  10 mL/L, serta SRP 1,5 N dan SRP 2 N dengan dosis 4 mL/L.

Keywords


koagulasi, koagulan, recovery lumpur, pengasaman

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References


Teh CY, Wu TY. The Potential Use of Natural Coagulants and Flocculants in The Treatment of Urban Waters. Chem. Eng. Trans. 2014; 39: 1603-1608

Teh CY, Budiman PM, Shak KPY, Wu TY. Recent Advancement of Coagulation-Flocculation and Its Application in Wastewater Treatment. Ind. Eng. Chem. Res. 2016; 55: 4363-4389

Niquette P, Monette F, Azzouz A, Hausler, R. Impacts of Substituting Aluminum-Based Coagulants in Drinking Water Treatment. Water Quality Research Journal of Canada. 2004; 39: 303-310

Keeley J, Jarvis P, Smith AD, Judd SJ. 2016. Coagulant Recovery and Reuse for Drinking Water Treatment. Water Research. 2016; 88: 502-509

Keeley J, Jarvis P, Judd S. Coagulant Recovery from Water Treatment Residuals: A Review of Applicable Technologies. Critical Reviews in Environmental Science and Technology. 2014; 44: 2675-2719

Sales A, De Souza FR, Almeida FR. 2011. Mechanical Properties of Concrete Produced with a Composite of Water Treatment Sludge and Sawdust. Constr. Build. Mater. 2011; 25: 2793-2798

Trinh TK, Kang LS. Response Surface Methodological Approach to Optimize The Coagulation-Flocculation Process in Drinking Water Treatment. Chemical Engineering Research and Design. 2011; 89: 1126-1135

Shak KPY, Wu TY. 2015. Optimized Use of Alum Together with Unmodified Cassiaobtusifolia Seed Gum as a Coagulant Aid in Treatment of Palm Oil Mill Effluent Under Natural Ph of Wastewater. Ind. Crop. Prod. 2015; 76: 1169-1178

Muisa N, Hoko Z, Chifamb P. 2011. Impacts of Alum Residues from Morton Jaffray Water Works on Water Quality and Fish, Harare, Zimbabwe. Phys. Chem. Earth Parts A/B/C. 2011; 36: 853-864

Xu GR, Zhang WT, Li GB. Absorbent Obtained from CEPT Sludge in Wastewater Chemically Enhanced Treatment. Water Research. 2005; 39: 5175–5185

Xu GR, Yan ZC, Wang YC, Wang N. 2009, Recycle of Alum Recovered from Watertreatment Sludge in Chemically Enhanced Primary Treatment. J. Hazard. Mater. 2009; 161: 663-669

Lin L, Li R, Li X. Recovery of Organic Resources from Sewage Sludge of Al-Enhanced Primary Sedimentation by Alkali Pretreatment and Acidogenic Fermentation. Journal of Cleaner Production. 2018; 172: 3334-3341

Nair AT , Ahammed MM. The Reuse of Water Treatment Sludge as a Coagulant for Post-Treatment of UASB Reactor Treating Urban Wastewater. Journal of Cleaner Production. 2015; 96: 272-281

Prakash P, Sengupta AK. 2003. Selective Coagulant Recovery from Water Treatment Plant Residuals Using Donnan Membrane Process. Environmental Science and Technology. 2003; 37: 4468-4474

Ahmad T, Ahmad K, Ahad A, Alam M. Characterization of Water Treatment Sludge and Its Reuse as Coagulant. Journal of Environmental Management. 2016; 182: 606-611

Huang S, Chen JL, Chiang KY, Wu CC. Effects of Acidification on Dewaterability and Aluminum Concentration of Alum Sludge. Separation Science and Technology. 2010; 45: 1165-1169

Suman A, Ahmad K, Haq I. Water Treatment Plant Sludge Characterization, Recovery of Coagulant and Its Reuse. International Journal of Research in Engineering and Technology. 2018; 7: 214-220

Javidparvar AA, Ramezanzadeh B, Ghasemi E. The Effect of Surface Morphology and Treatment of Fe3O4 Nanoparticles on The Corrosion Resistance of Epoxy Coating. Journal of The Taiwan Institute Of Chemical Engineers. 2016; 61: 356-366

Ramalla I, Gupta RK, Bansal K. Effect on Superhydrophobic Surfaces on Electrical Porcelain Insulator, Improved Technique at Polluted Areas for Longer Life and Reliability. International Journal of Engineering & Technology. 2015; 4: 509-519

Mooheng P, Phenrat T. Acid-Assisted Recycling Of Fe(OH)3 Sludge as Coagulant for Metalworking Fluid Wastewater Treatment. The NAXOS 2018 6th International Conference on Sustainable Solid Waste Management. Greece. 2018: 1-10

Joshi S, Shrivastava K. Recovery of Alum Coagulant from Water Treatment Plant Sludge: A Greener Approach for Water Purification. International Journal of Advanced Research. 2011; 1: 101-103

Subramonian W, Wu TY, Chai SP. 2014. A Comprehensive Study on Coagulant Performance and Floc Characterization of Natural Cassia Obtusifolia Seed Gum in Treatment of Raw Pulp and Paper Mill Effluent. Industrial Crops and Products. 2014; 61: 317-324

Oriekhova O, Stoll S. Investigation Of FeCl3 Induced Coagulation Processes Using Electrophoretic Measurement, Nanoparticle Tracking Analysis and Dynamic Light Scattering: Importance of Ph and Colloid Surface Charge. Colloids and Surfaces A: Physicochem. Eng. Aspects. 2014; 461: 212-219

Wulan PP, Dianursanti D, Gozan M, Nugroho WA. 2010. Optimasi Penggunaan Koagulan pada Pengolahan Air Limbah Batu Bara. Seminar Nasional Teknik Kimia Kejuangan. Yogyakarta. 2010: F06-1-6

Chuan CB, Yu GB, Hua XC, Ying F. Effects of Ph on Coagulation Behavior and Floc Properties in Yellow River Water Treatment Using Ferric Based Coagulants. Chinese Science Bulletin. 2010; 55: 1382-1387

Padmavathy KS, Madhu G, Haseena PV. A Study on Effects of Ph, Adsorbent Dosage, Time, Initial Concentration and Adsorption Isotherm Study for The Removal of Hexavalent Chromium (Cr (VI)) from Wastewater by Magnetite Nanoparticles. Procedia Technology. 2016; 24: 585-594.

Pang FM, Kumar P, Teng TT, Omar AKM, Wasewar KL. Removal of Lead, Zinc and Iron by Coagulation-Flocculation. Journal of the Taiwan Institute of Chemical Engineers. 2011; 42(5): 809-815




DOI: http://dx.doi.org/10.26578/jrti.v12i2.4192



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Akreditasi S2 Vol.10 No.1 th 2016 s/d Vol.14 No.2 th 2020. p-ISSN : 1978-6891, e-ISSN : 2541-5905. 

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