Perlakuan ozon dan sonokimia untuk degradasi residu mankozeb pada cabe hijau (Capsicum annuum L.)

Safni Safni; Elma Fadrita Rahman; Deswati Deswati; Salmariza Sy

doi:10.24960/jli.v11i2.7259.103-109

Perlakuan ozon dan sonokimia untuk degradasi residu mankozeb pada cabe hijau (Capsicum annuum L.)

Safni Safni, Elma Fadrita Rahman, Deswati Deswati, Salmariza Sy

Abstract

Fungisida, seperti mankozeb, banyak digunakan dalam bidang pertanian berkelanjutan dan akan meninggalkan residu pada bahan pangan. Proses oksidasi lanjutan (AOPs) ozon treatment (ozonolisis dan air ozon), sonokimia (sonolisis) serta kombinasi keduanya (sonozolisis) merupakan salah satu teknik potensial dalam mendegradasi residu mankozeb pada cabe hijau. Perbandingan metode degradasi dilakukan pada kondisi yang sama yakni 50 g cabe hijau, 100 mL air dengan waktu treatment 10 menit mampu mendegradasi residu mankozeb sebesar 69,63±1,60 air ozon; 58,83±2,57 sonozolisis; 56,51±2,29 ozonolisis; dan 23,70±1,60 sonolisis. Penambahan waktu perendaman selama 20 menit air ozon meningkatkan persentase degradasi sebesar 83,80±2,54. Beberapa parameter yang mempengaruhi proses degradasi dipelajari seperti waktu treatment, volume air, dan massa cabe hijau. Proses degradasi dengan waktu treatment 10-15 menit, volume air 100 mL dan 50 g cabe hijau mampu mereduksi residu mankozeb sebesar 25-58%. Data hasil analisis spektrofotometer-HPLC menunjukkan bahwa residu mankozeb pada cabe hijau telah berhasil didegradasi.

Keywords

cabe hijau; degradasi; ozon; residu mankozeb; sonokimia

Full Text:

PDF (Indonesian)

References

Amelia, F., Safni, Suyani, H., 2015. Degradasi senyawa imidakloprid secara advanced oxidation processes dengan penambahan TiO2-Anatase. J. Ris. Kim. 8, 108. https://doi.org/10.25077/jrk.v8i2.225

Arfi, F., Safni, S., Abdullah, Z., 2017. Degradation of paraquat in gramoxone pesticide with addition of ZnO. Molekul 12, 159. https://doi.org/10.20884/1.jm.2017.12.2.326

Azam, S.M.R., Ma, H., Xu, B., Devi, S., Bakar, A., Stanley, S.L., Bhandari, B., Zhu, J., 2020. Efficacy of ultrasound treatment in the and removal of pesticide residues from fresh vegetables : A review. Trends Food Sci. Technol. 97, 417–432. https://doi.org/10.1016/j.tifs.2020.01.028

Bianchi, S., Nottola, S.A., Torge, D., Palmerini, M.G., Necozione, S., Macchiarelli, G., 2020. Association between female reproductive health and mancozeb: Systematic review of experimental models. Int. J. Environ. Res. Public Health 17. https://doi.org/10.3390/ijerph17072580

Cengiz, M.F., Başlar, M., Basançelebi, O., Kılıçlı, M., 2018. Reduction of pesticide residues from tomatoes by low intensity electrical current and ultrasound applications. Food Chem. 267, 60–66. https://doi.org/10.1016/j.foodchem.2017.08.031

Chanrattanayothin, P., Peng-Ont, D., Masa-Ad, A., Warisson, T., Nirunsin, R., Sintuya, H., 2020. Degradation of cypermethrin and dicofol pesticides residue in dried basil leave by gaseous ozone fumigation. Ozone Sci. Eng. 42, 469–476. https://doi.org/10.1080/01919512.2019.1708699

Chen, J.Y., Lin, Y.J., Kuo, W.C., 2013. Pesticide residue removal from vegetables by ozonation. J. Food Eng. 114, 404–411. https://doi.org/10.1016/j.jfoodeng.2012.08.033

Deng, Y., Zhao, R., 2015. Advanced Oxidation Processes (AOPs) in wastewater treatment. Curr. Pollut. Reports 1, 167–176. https://doi.org/10.1007/s40726-015-0015-z

Fitriadi, B.R., Putri, A.C., 2016. Metode-metode pengurangan residu pestisida pada hasil pertanian. J. Rekayasa Kim. Lingkung. 11, 61. https://doi.org/10.23955/rkl.v11i2.4950

Gligorovski, S., Strekowski, R., Barbati, S., Vione, D., 2015. Environmental implications of hydroxyl radicals (•OH). Chem. Rev. 115, 13051–13092. https://doi.org/10.1021/cr500310b

Heleno, F.F., De Queiroz, M.E.L.R., Faroni, L.R.A., Neves, A.A., De Oliveira, A.F., Costa, L.P.L., Pimenta, G.G., 2016. Aqueous ozone solutions for pesticide removal from potatoes. Food Sci. Technol. Int. 22, 752–758. https://doi.org/10.1177/1082013216651179

Heshmati, A., Nazemi, F., 2018. Dichlorvos (DDVP) residue removal from tomato by washing with tap and ozone water, a commercial detergent solution and ultrasonic cleaner. Food Sci. Technol. 38, 441–446. https://doi.org/10.1590/1678-457x.07617

Ibrahim, K.E.A., Şolpan, D., 2020. Removal of carbaryl pesticide in aqueous solution by UV and UV/hydrogen peroxide processes. Int. J. Environ. Anal. Chem. 00, 1–15. https://doi.org/10.1080/03067319.2020.1767091

Ikeura, H., Kobayashi, F., Tamaki, M., 2013. Ozone microbubble treatment at various water temperatures for the removal of residual pesticides with negligible effects on the physical properties of lettuce and cherry tomatoes. J. Food Sci. 78, T350–T355. https://doi.org/10.1111/1750-3841.12007

Khoiriah, K., Safni, S., Syukri, S., Gunlazuardi, J., 2020a. Photocatalytic ozonation using C,N-Codoped TiO2 for diazinon degradation. J. Chem. Technol. Metall. 55, 2120–2127.

Khoiriah, K., Safni, S., Syukri, S., Gunlazuardi, J., 2020. The operational parameters effect on photocatalytic degradation of diazinon using carbon and nitrogen modified TiO2. Rasayan J. Chem. 13, 1919–1925. https://doi.org/10.31788/RJC.2020.1335743

Khoiriah, K., Wellia, D.V., Gunlazuardi, J., Safni, S., 2020b. Photocatalytic degradation of commercial diazinon pesticide using C,N-codoped TiO2 as photocatalyst. Indones. J. Chem. 20, 587. https://doi.org/10.22146/ijc.43982

Khoiriah, K., Wellia, D.V., Safni, S., 2019. Degradasi pestisida diazinon dengan proses fotokatalisis sinar matahari menggunakan katalis C,N-Codoped TiO2. J. Kim. dan Kemasan 41, 17. https://doi.org/10.24817/jkk.v41i1.3834

Lozowicka, B., Jankowska, M., Hrynko, I., Kaczynski, P., 2016. Removal of 16 pesticide residues from strawberries by washing with tap and ozone water, ultrasonic cleaning and boiling. Environ. Monit. Assess. 188, 51. https://doi.org/10.1007/s10661-015-4850-6

Pandiselvam, R., Kaavya, R., Jayanath, Y., Veenuttranon, K., Lueprasitsakul, P., Divya, V., Kothakota, A., Ramesh, S. V, 2020. Ozone as a novel emerging technology for the dissipation of pesticide residues in foods–a review. Trends Food Sci. Technol. https://doi.org/10.1016/j.tifs.2019.12.017

Pirsaheb, M., Moradi, N., 2020. Sonochemical degradation of pesticides in aqueous solution: Investigation on the influence of operating parameters and degradation pathway-a systematic review. RSC Adv. 10, 7396–7423. https://doi.org/10.1039/c9ra11025a

Putri, R.A., Safni, S., Wellia, D.V., Septiani, U., Jamarun, N., 2019. Degradasi zat warna orange-F3R dan Violet-3B secara sonolisis frekuensi rendah dengan penambahan katalis C-N-Codoped TiO2. J. Kim. Val. 5, 35–43. https://doi.org/10.15408/jkv.v5i1.7801

Rodrigues, A.A.Z., Queiroz, M.E.L.R. de, Neves, A.A., Oliveira, A.F. de, Prates, L.H.F., Freitas, J.F. de, Heleno, F.F., Faroni, L.R.D.A., 2019. Use of ozone and detergent for removal of pesticides and improving storage quality of tomato. Food Res. Int. 125, 108626. https://doi.org/10.1016/j.foodres.2019.108626

Safni, S., Anggraini, D., Wellia, D., Khoiriah, K., 2015. Degradation of direct red-23 and direct violet dyes by ozonolysis and photolysis methods with UV light and solar irradiation using N-Doped TiO2 catalyst. J. Litbang Ind. 5, 123–130.

Saleh, I.A., Zouari, N., Al-Ghouti, M.A., 2020. Removal of pesticides from water and wastewater: Chemical, physical and biological treatment approaches. Environ. Technol. Innov. 19, 101026. https://doi.org/10.1016/j.eti.2020.101026

Saravi, S., Shokrzadeh, M., 2016. Effects of washing, peeling, storage, and fermentation on residue contents of carbaryl and mancozeb in cucumbers grown in greenhouses. Toxicol. Ind. Health 32, 1135–1142. https://doi.org/10.1177/0748233714552295

Savi, G.D., Piacentini, K.C., Bortolotto, T., Scussel, V.M., 2016. Degradation of bifenthrin and pirimiphos-methyl residues in stored wheat grains ( Triticum aestivum L.) by ozonation. Food Chem. 203, 246–251. https://doi.org/10.1016/j.foodchem.2016.02.069

Stefan, M.I., 2019. Advanced oxidation processes for water treatment. IWA Publishing, London SW1H 0QS, UK.

Tzortzakis, N., Chrysargyris, A., 2017. Postharvest ozone application for the preservation of fruits and vegetables. Food Rev. Int. 33, 270–315. https://doi.org/10.1080/87559129.2016.1175015

Wang, S., Wang, J., Li, C., Xu, Y., Wu, Z., 2021. Ozone treatment pak choi for the removal of malathion and carbosulfan pesticide residues. Food Chem. 337, 127755. https://doi.org/10.1016/j.foodchem.2020.127755

Wang, S., Wang, J., Wang, T., Li, C., Wu, Z., 2019. Effects of ozone treatment on pesticide residues in food: a review. Int. J. Food Sci. Technol. 54, 301–312. https://doi.org/10.1111/ijfs.13938

Zhu, Y., Zhang, T., Xu, D., Wang, S., Yuan, Y., He, S., Cao, Y., 2019. The removal of pesticide residues from pakchoi (Brassica rape L. ssp. chinensis) by ultrasonic treatment. Food Control 95, 176–180. https://doi.org/10.1016/j.foodcont.2018.07.039

DOI: http://dx.doi.org/10.24960/jli.v11i2.7259.103-109