Hidroksiapatit sintetik Balai Besar Keramik (BBK) sebagai material baru filter tabir surya

Rizky Berliana Wijayanti; Imas Panca Wardhani; Kristanto Wahyudi

doi:10.24960/jli.v11i1.6746.33-38

Hidroksiapatit sintetik Balai Besar Keramik (BBK) sebagai material baru filter tabir surya

Rizky Berliana Wijayanti, Imas Panca Wardhani, Kristanto Wahyudi

Abstract

Balai Besar Keramik (BBK) telah berhasil mensintesis hidroksiapatit (HA) dari sumber daya alam Indonesia yaitu batu kapur Padalarang dan Cirebon dengan metode presipitasi basah. Berbagai aplikasi yang dapat menggunakan hidroksiapatit sintetik ini antara lain: bone china, kandidat bone grafting, tulang cacat femoralis cavia cobaya, implan tulang berbahan komposit Al-HA dan material karbonat hidroksiapatit. HA merupakan bahan yang non fotokatalitik oleh karena itu tidak akan menimbulkan munculnya radikal bebas. Studi ini meneliti aplikasi dan sifat hidroksiapatit BBK sintetis sebagai bahan filter tabir surya baru. Kristalinitas, ukuran kristal dan mineralogi HA sintetik dikarakterisasi dengan XRD. Kemampuan dalam menyerap radiasi sinar UV dianalisis dengan UV-Vis kemudian nilai faktor SPF dihitung secara in vitro menggunakan persamaan Mansur. Dari hasil analisis UV-Vis menunjukkan bahwa hidroksiapatit sintetis BBK memiliki absorbsi pada panjang gelombang 280-410 nm. Dari perhitungan didapatkan nilai SPF sebesar 8,82.

Keywords

hidroksiapatit; BBK; tabir surya; SPF; Mansur

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References

Amin, R.M., Elfeky, S.A., Verwanger, T., Krammer, B., 2016. A new biocompatible nanocomposite as a promising constituent of sunscreens. Mater. Sci. Eng. C 63, 46–51.

Buescher, L.S., 1993. Sunscreens and photoprotection, Otolaryngologic Clinics of North America. https://doi.org/10.1016/s0030-6665(20)30863-x

C. Teixeira, M.A., Piccirillo, C., Tobaldi, D.M., Pullar, R.C., Labrincha, J.A., Ferreira, M.O., L. Castro, P.M., E. Pintado, M.M., 2016. Effect of preparation and processing conditions on UV absorbing properties of hydroxyapatite-Fe2O3 sunscreen. Mater. Sci. Eng. C 71, 141–149.

Cole, C., Shyr, T., Ou-Yang, H., 2016. Metal oxide sunscreens protect skin by absorption, not by reflection or scattering. Photodermatol. Photoimmunol. Photomed. 32, 5–10. https://doi.org/10.1111/phpp.12214

Damayanti, H., Ratnasari, A., Wahyudi, K., 2018. Karakteristik kromatik bone ash sintetik berdasarkan suhu kalsinasi. J. Keramik dan Gelas Indones. 27, 66–76.

De Araujo, T.S., De Souza, S.O., De Sousa, E.M.B., 2010. Effect of Zn2+, Fe3+ and Cr3+ addition to hydroxyapatite for its application as an active constituent of sunscreens. J. Phys. Conf. Ser. 249.

Egambaram, O.P., Kesavan Pillai, S., Ray, S.S., 2020. Materials science challenges in skin UV protection: A review. Photochem. Photobiol. 96, 779–797.

Geoffrey, K., Mwangi, A.N., Maru, S.M., 2019. Sunscreen products: Rationale for use, formulation development and regulatory considerations. Saudi Pharm. J. 27, 1009–1018.

Hoang, B.T.X., Popa, I., 2014. Innovation in inorganic UV filters in sunscreen. Househ. Pers. Care Today 9, 35–39.

Isfardiyana, S.H., Safitri, S.R., 2014. Pentingnya melindungi kulit dari sinar ultraviolet dan cara melindungi kulit dengan sunblock buatan sendiri. J. Inov. dan Kewirausahaan 3, 126–133.

Pal, A., Hadagalli, K., Bhat, P., Goel, V., Mandal, S., 2020. Hydroxyapatite—a promising sunscreen filter. J. Aust. Ceram. Soc. 56, 345–351.

Piccirillo, C., Rocha, C., Tobaldi, D.M., Pullar, R.C., Labrincha, J.A., Ferreira, M.O., Castro, P.M.L., Pintado, M.M.E., 2012. A hydroxyapatite-Fe2O3 based material of natural origin as an active sunscreen filter. J. Mater. Chem. B 2, 5999–6009.

Pirotta, G., 2020. Sunscreen regulation in the world. Handb. Environ. Chem. 94, 15–35.

Pridanti, K.A., 2020. Characteristic and cytotoxicity of hyrdroyapatite from Padalarang-Cirebon limestone as bone grafting candidate. Biochem. Cell. Arch. 20.

Rianti, D., Yulianti, A., Wahyudi, K., Damayanti, H., 2020. Limestone-based hydroxyapatite use for cavia cobaya femoral bone defects. Biochem. Cell. Arch. 2.

Rigano, L., Lionetti, N., 2016. Nanobiomaterials in galenic formulations and cosmetics, Nanobiomaterials in Galenic Formulations and Cosmetics: Applications of Nanobiomaterials. Elsevier Inc.

Rozaini, M.Z.H., Hamzah, H., Mohtar, N.F., Razali, M.H., Ibrahim, N.H., 2018a. Characterization of photoprotective hydroxiapatite from fringescale sardinella (Valenciennes, 1847) bones as natural sunscreen for cosmeceutical treatments. Key Eng. Mater. 792, 67–73.

Rozaini, M.Z.H., Hamzah, H., Poh Wai, C., Razali, M.H., M. Osman, U., Tuan Anuar, S., Che Soh, S.K., Binti Ghazali, S.R., Ibrahim, N.H., Fei, low C., Rahmah, S., 2018b. Calcium hydroxyapatite-based marine origin: Novel sunscreen materials for cosmeceutical treatments. Orient. J. Chem. 34, 2770–2776.

Sliem, M.A., Karas, R.A., Harith, M.A., 2017. A promising protected ascorbic acid-hydroxyapatite nanocomposite as a skin anti-ager: A detailed photo-and thermal stability study. J. Photochem. Photobiol. B Biol. 173, 661–671.

Tahiliani, S., Shirolikar, M., 2018. Viva voce on sunscreens. Indian J. Drugs Dermatology 4, 92.

Wahyudi, K., Edwin, F., Sofiyaningsih, N., 2016. Sintetis dan karakterisasi bone ash sintetik dari bahan alam. J. Keramik dan Gelas Indones. 2.

DOI: http://dx.doi.org/10.24960/jli.v11i1.6746.33-38