Synthesis And Characterization of Hydroxyapatite-Gibbsite
Abstract
Hydroxyapatite (HAp) is a material that is often used in biomedical applications. However, this material has poor mechanical properties so that its use is still limited and needs to be modified by adding other materials to obtain better mechanical properties. In this study, synthesis was carried out by adding gibbsite to HAp with variations in the ratio of HAp/gibsite (% by weight) and heating at 1200oC for 2 hours. The results obtained are HAp-Gibsite which has a change in the mineral phase and mechanical properties according to the ratio of HAp/Gibsite (% by weight). The mechanical properties of the sample increased with the addition of gibbsite up to 60% by weight with the best conditions achieved with the addition of 20% gibbsite, namely the compressive strength value of 227 Mpa and vicker hardness of 5.54 Gpa. The addition of gibbsite greater than 60% by weight tends to cause a decrease in the mechanical properties of the sample due to the more decomposition of HAp into -TCP and the effect of excess alumina which increases the porosity of the sample
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A. Setiawan, W. Widiyastuti, S. Winardi, and A. Nugroho, “Sintesis Biomaterial Hydroxyapatite Dengan Proses Flame Spray Pyrolysis Disertai Penambahan Aditif Organik,” Reaktor, vol. 16, no. 4, p. 189, 2017, doi: 10.14710/reaktor.16.4.189-198.
K. Jahan, G. Manickam, M. Tabrizian, and M. Murshed, “In vitro and in vivo investigation of osteogenic properties of self-contained phosphate-releasing injectable purine-crosslinked chitosan-hydroxyapatite constructs,” Sci. Rep., vol. 10, no. 1, pp. 1–17, 2020, doi: 10.1038/s41598-020-67886-7.
A. Jaafar, C. Hecker, P. Á, and Y. Joseph, “Sol-Gel Derived Hydroxyapatite Coatings for Titanium Implants : A Review,” 2020.
S. Safi, F. Karimzadeh, and S. Labbaf, “Mesoporous and hollow hydroxyapatite nanostructured particles as a drug delivery vehicle for the local release of ibuprofen,” Mater. Sci. Eng. C, p. #pagerange#, 2018, doi: 10.1016/j.msec.2018.07.004.
N. A. Nawawi, A. S.F. Alqap, and I. Sopyan, “Recent Progress on Hydroxyapatite-Based Dense Biomaterials for Load Bearing Bone Substitutes,” Recent Patents Mater. Sci., vol. 4, no. 1, pp. 63–80, 2011, doi: 10.2174/1874465611104010063.
M. Mathina, E. Shinyjoy, L. Kavitha, and D. Gopi, Biowaste-derived hydroxyapatite reinforced with polyvinyl pyrrolidone/aloevera composite for biomedical applications, vol. 18, no. 1. 2021.
J. Dou, C. Zhang, C. Chen, and X. Zhang, “Effects of sintering temperature on the properties of alumina / hydroxyapatite composites Effects of sintering temperature on the properties of alumina / hydroxyapatite composites,” J. Sol-Gel Sci. Technol., no. August, 2017, doi: 10.1007/s10971-017-4492-y.
J. Zhang et al., “Zirconia toughened hydroxyapatite biocomposite formed by a DLP 3D printing process for potential bone tissue engineering,” Mater. Sci. Eng. C, vol. 105, no. August, p. 110054, 2019, doi: 10.1016/j.msec.2019.110054.
M. Yetmez, Z. E. Erkmen, C. Kalkandelen, A. Ficai, and F. N. Oktar, “Sintering effects of mullite-doping on mechanical properties of bovine hydroxyapatite,” Mater. Sci. Eng. C, vol. 77, pp. 470–475, 2017, doi: 10.1016/j.msec.2017.03.290.
A. Pramono, F. Sulaiman, and A. Milandia, “Fabrication of metal matrix composites based on hydroxyapatite by self-high propagating temperatures synthesis ( SHS ),” no. August, 2020, doi: 10.20944/preprints202008.0596.v1.
M. G. De Lima, E. Leal, E. M. D. J. Agnolon Pallone, R. H. G. A. Kiminami, and A. C. F. D. M. Costa, “Microstructural and mechanical properties of Al2O3/HAp composites for use as bone substitute material,” Mater. Sci. Forum, vol. 912 MSF, pp. 153–158, 2018, doi: 10.4028/www.scientific.net/MSF.912.153.
X. Zhang et al., “Boehmite and Gibbsite Nanoplates for the Synthesis of Advanced Alumina Products,” ACS Appl. Nano Mater., vol. 1, no. 12, pp. 7115–7128, 2018, doi: 10.1021/acsanm.8b01969.
M. N. Ahmadabadi, A. Nemati, K. Arzani, and S. Baghshahi, “The relation between particle size and transformation temperature of gibbsite to αLPHA-alumina,” Miner. Process. Extr. Metall. Trans. Inst. Min. Metall., vol. 0, no. 0, pp. 1–11, 2020, doi: 10.1080/25726641.2020.1815504.
A. C. V. Coelho, H. S. Santos, P. K. Kiyohara, and P. S. Santos, “Surface area and crystal morphology of alumina powders by thermal activation of a gibbsite precursor prepared by a new procedure,” pp. 1534–1538, 2002.
A. E. Hannora, “Preparation and characterization of hydroxyapatite/alumina nanocomposites by high-energy vibratory ball milling,” J. Ceram. Sci. Technol., vol. 5, no. 4, pp. 293–298, 2014, doi: 10.4416/JCST2014-00019.
R. R. Rao and T. S. Kannan, “Synthesis and sintering of hydroxyapatite in presence of oxide additives,” Trans. Indian Ceram. Soc., vol. 58, no. 3, pp. 64–68, 1999, doi: 10.1080/0371750X.1999.10799863.
B. Viswanath and N. Ravishankar, “Interfacial reactions in hydroxyapatite/alumina nanocomposites,” Scr. Mater., vol. 55, no. 10, pp. 863–866, 2006, doi: 10.1016/j.scriptamat.2006.07.049.
R. Salomão, V. L. Ferreira, I. R. de Oliveira, A. D. V. Souza, and W. R. Correr, “Mechanism of pore generation in calcium hexaluminate (CA6) ceramics formed in situ from calcined alumina and calcium carbonate aggregates,” J. Eur. Ceram. Soc., vol. 36, no. 16, pp. 4225–4235, 2016, doi:10.1016/j.jeurceramsoc.2016.05.026.
N. A. Moslim, C. Y. Beh, S. R. Kasim, and S. Ramakrishnan, “Effect of Composition and Temperature to the HA/ß-TCP Composite,” J. Phys. Conf. Ser., vol. 1082, no. 1, 2018, doi: 10.1088/1742-6596/1082/1/012023.
DOI: http://dx.doi.org/10.32537/jkgi.v30i2.7278
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