The Preparation Hydroxyapatite – Zirconia Composites as Bioceramic Materials

Eneng Maryani, Sri Cicih Kurniasih, Naili Sofiyaningsih, Bayu Priyanto

Abstract


Hydroxyapatite (HAP) is a material often used as a bioceramic because of its special characteristics such as has the same mineral composition as the original bone and teeth, does not cause cytotoxic effects, biocompatible, bioactive and promote osteoconductivity. However HAP shows poor mechanical properties so it is less applicable to biological applications that must accept heavy loads. Therefore, it is necessary to modify the hydroxyapatite structure through the process of reinforcement (composite formation) with other materials such as zirconia (ZrO2). In this research, hydroxyapatite – zirconia composite prepared from each component made from local natural mineral. The compositions of prepared hydroxyapatite – zirconia composites are 75:25, 50:50, and 25:75. In all composite compositions prepared after calcination at 1000 oC, hydroxyapatite phase change into whitlockite and tetrahedral zirconia phase formed. Composite of HAP-ZrO2 =75:25 is the most suitable proportion because they still the highest hydroxyapatite content and all zirconia is in the tetrahedral phase


Keywords


bioceramic, hydroxyapatite, zirconia, composite, whitlockite, tetrahedral, calcination

Full Text:

PDF

References


B. Bulut, Z.E. Erkmen, E.S. Kayali, “Biocompatibility of Hydroxyapatite-Alumina and Hydroxyapatite-Zirconia Composite including Commercial Inert Glass (CIG) as a Ternary Component”, J. Ceram. Sci. Tech., 2016, 07(03), 263-276

K. Prabakaran, S. Kannan & S. Rajeswari, “Development and Characterisation of Zirconia and Hydroxyapatite Composites for Orthopaedic Application”, Trends Biomater. Artif. Organs, 2005, 18(2), 114-116

S.S. Baidya, “Preparation and Characterization of Hydroxyapatite – Zirconia Composite”, Thesis, Dept. of Ceramic Eng., National Institute of Technology, Rourkela, 2013

F. Mohamaddoost, H.M. Yusoff, K.A. Matori, F. Ostovan, & G.R. Vahedi, “Bio Ceramic Zirconia/Hydroxyapatite Nano Composite Extracted from Bovine Bone”, Australian Journal of Basic and Applied Sciences, 2014, 8(15), 302-306

J.S. Al-Sanabani, A.A. Madfa & F.A. Al-Sanabani, “Application of Calcium Phosphate Materials in Dentistry”, International Journal of Biomaterials, 2013, 1-12

J.A. Nordin, D.H. Prajitno, S. Saidin, H. Nur, & H. Hermawan, “Structure-Property Relationships of Iron-Hydroxyapatite Ceramic Matrix Nanocomposite Fabricated using Mechanosynthesis Method”, Materials Science and Engineering, 2015, C 51, 294-299

S. Awasthi, “A Study on Structural Properties of Hydroxyapatite – Zirconia Composites” Thesis, Dept. of Ceramic Eng., National Institute of Technology, Rourkela, 2015

M.G. Kutty & R. Singh, “The Effects of Zirconia Additions on the Sintering Behaviour and Phase Stability of Hydroxyapatite Ceramics”, Pertanika J. Sci. & Technol., 2001, Supplement, 9(2), 229-238

J. Brzezińska-Miecznik, K. Haberko, M.M. Bućko, G. Grabowski & M. Sitarz, “Hydroxyapatite of Natural Origin – Zirconia Composites, Preparation and Reactions within the System”, Processing and Application of Ceramics, 2016, 10(4), 219-225

E. Karamian, A. Nasehi, S. Saber-Samandari, & A. Khandan, “Fabrication of Hydroxyapatite-Baghdadite Nanocomposite Scaffolds Coated by PCL/Bioglass with Polyurethane Polymeric Sponge Technique”, Nanomed. J., 2017, 4(3), 177-183

T. Laonapakul, “Synthesis of Hydroxyapatite from Biogenic Wastes”, KKU Engineering Journal, 2015, 42(3), 269-275

S. Rahardjo, Suhanda, U. Karsono & N.Sofiyaningsih, “Teknologi Destruksi Sintering untuk Perolehan ZrO2 dan SiO2 dari Pasir Zirkon”, Prosiding Seminar Nasional Keramik XIV, 27 Mei 2015, 90-105

K. Wahyudi, F. Edwin & N. Sofiyaningsih, “Sintesis dan Karakterisasi Bone Ash Sintetik dari Bahan Alam”, Jurnal Keramik dan Gelas Indonesia, 2016, 25(2), 46-58

K.Obradović-Djuričić, V.Medić, S. Dodić, D. Gavrilov, D. Antonijević & M. Zrilić, “Dilemmas in Zirconia Bonding: A Review”, Srp Arh Celok Lek., 2013, 141(5-6), 395-401M.R. Gauna, M.S. Conconi, S. Gomez, G. Suarez, E.F. Aglietti, & N.M. Rendtorff, “Monoclinic – Tetragonal Zirconia Quantification of Commercial Nanopowder Mixtures by XRD and DTA”, Ceramics – Silikáty, 2015, 59(4), 318-325

D.V. Deyneko, S.M. Aksenov, V.A. Morozov, S.Y. Stefanovich, O.V. Dimitrova, O.V. Barishnikova & B.I. Lazoryak, “ A New Hydrogen-Containing Whitlockite-Type Phosphate Ca9(Fe0,63Mg0,37)H0,37(PO4)7: Hydrothermal Synthesis and Structure”, Z. Kristallogr., 2014, 229(12), 823-830

E. ŞAHİN, “Synthesis and Characterization of Hydroxyapatite-Alumina-Zirconia Biocomposites”, Thesis, 2006, Engineering and Sciences of Izmir Institute of Technology

B.S. Purwasasmita & E. Maryani, “Inovasi dan Teknik Fabrikasi Material Biokeramik”, JKGI, 2007, 16(1), 45-56

B.S. Purwasasmita & E. Maryani, “Inovasi dan Teknik Fabrikasi Material Biokeramik”, JKGI, 2007, 16(1), 45-56

Y. Avnimelech, E.C. Moreno, & W.E. Brown, “Solubility and Surface Properties of Finely Divided Hydroxyapatite”, J. of Research of the National Bureau of Standards, 77A(1), 1973

Q. Ge, “Synthesis and Characterization of Mesoporous Zirconia Nanocomposite Using Self-Assembled Block Copolymer Template”, Graduate Theses and Dissertations, 2012, Iowa State University




DOI: http://dx.doi.org/10.32537/jkgi.v27i1.4038

Refbacks

  • There are currently no refbacks.



JKGI Google Scholar Link



Lisensi Creative Commons
Ciptaan disebarluaskan di bawah Lisensi Creative Commons Atribusi-NonKomersial-BerbagiSerupa 4.0 Internasional.