PENGARUH ABU SEKAM PADI DAN COUPLING AGENT TERHADAP KETAHANAN USANG VULKANISAT BANTALAN DERMAGA
Abstract
The research aimed to study the ageing resistance of vulcanized dock vendor with rice husk ash filler and coupling agent. The experimental research used non Factorial Completely Randomized Design and each treatments was replicated three times. Single factor concentration of ratio of rice husk ash and coupling agent 3-methacryloxypropyl trimethoxysilane (MPS) (70 phr: 1 phr, 100 phr: 1 phr, 130 phr: 1 phr, 160 phr: 1 phr, 190 phr: 1 phr and 220 phr : 1 phr). The parameters were hardness, tensile strength, elongation at break and ageing resitance before and after ageing. The results showed that all treatments have a influence on vulcanized dock fendor and meet the quality requirements SNI 06-3568-2006 for treatment concentration of ASP70 tol ASP160 with characteristics hardness of 70 Shore A, 75 Shore A, 78 Shore A dan 80 Shore A after ageing 68 Shore A, 72 Shore A, 76 Shore A dan 78 Shore A. The tensile strength before (19 N / mm2, 21 N / mm2, 17 N / mm2 and 16 N / mm2), after ageing (17 N / mm2, 20 N / mm2, 15 N / mm2 and 15 N / mm2). ASP70 to ASP220 treatment concentration up to the elongation at break before (350%, 345%, 330%, 220%, 209% and 200%), after ageing (343%, 335%, 325%, 216% and 200%). Tear resistance characteristics before (15.6 kg / cm, 17.2 kg / cm, 17.9 kg / cm, 18.2 kg / cm, 19 kg / cm and 20 kg / cm), after ageing (15 kg / cm, 16.1 kg / cm, 17.5 kg / cm, 17.9 kg / cm, 18.7 kg / cm.
Keywords
References
Alkadasi. N. A.N, Hundiwale. D.G and Kapadi. U.R. 2004. The Effect of SIlane Agent (2.0 per cent) on The Mechanical Properties of Flyash Filled Polybutadiena Rubber. Journal of Scientific & Industrial Research. 63 : 603 – 609.
Bahruddin, Saktiani. L, Yanuar dan Satoto. R. 2012. Pemanfaatan Limbah Fly Ash Pabrik Kelapa Sawit sebagai Filler Substitusi untuk Material Karet Alam Termoset: Pengaruh Nisbah Fly Ash/Carbon Black dan Kadar Coupling agent Maleated Natural Rubber. Prosiding InSINAS. Hal : 61 – 65.
Choi, Sung-Seen. 2000. Influence of Silane Coupling agent on Properties of Filled Styrena-Butadiena Rubber Compounds. Korea Polym Journal. 8 (6) : 285 – 291.
Choi, Sung-Seen and Choi Seok-Ju. 2006. Influence of Silane Coupling agent on Crosslink Type and Density of Silica-Filled Natural Rubber Vulcanizates. Bulletin Korean Chemical Society. 27(9) : 1473-1476.
Costa, H.M , L, Visconte. L. Y, Nunes, R. C. R dan Furtado, C. R. G. 2010. Rice Husk Ash Filled Natural Rubber Compounds – The Use of Rheometric Data to Qualitatively Estimate Optimum Filler Loading. International Journal of Polymeric Materials. 52 : 242 - 249
Daud. S, Ismail. H, Azhar, A. B. 2016. The Effect of 3-aminopropyltrimethyoxysilane (AMEO) as a Coupling Agent on Curing and Mechanical Properties of Natural Rubber/Palm Kernel Shell Powder Composites. Procedia Chemistry 19 (2) : 327 – 334
Imoisili1, P.E, Ukoba, K.O, Adejugbe, I.T, Adgidzi.D, Olusunle, S.O.O. 2013. Mechanical Properties of Rice Husk /Carbon Black Hybrid Natural Rubber Composite. Chemistry and Materials Research. 3(8) : 11 - 17
Katueangngana. K, Tulyapitaka. T, Saetunga. A, Soontaranon. S, Nattapong. N. 2016. Renewable Interfacial Modifier for Silica Filled Natural Rubber Compound. Procedia Chemistry 19(1): 447 – 454.
Louis, S.M, Shibu, N.V, Thomas, S. 2012. Effect of Rice Husk Ash on Mechanical Properties of Styrene-Butadiene Rubber. The IUP Journal of Mechanical Engineering, V(2) : 21-27.
Malekzadeh. M, Hesam. N, and Farahani. M. 2010. Investigation on The Influence of Silane Coupling Agent Structure on The Properties of Nano-Silica Filled Rubber Compound. Journal of Applied Chemical Researches. Hal 41-45.
Mazlina, M.K. ,Ibrahim.I, And Jane Clarke. 2010. Increasing the Interaction between Starch and the Rubber Matrix by Coupling agent Addition. J. Rubb. Res., 13(3), 139–161.
Nanda, H.N, Bahruddin dan Fadli, Ahmad. 2014. Pengaruh Maleated Natural Rubber Terhadap Morfologi dan Sifat Thermoset Rubber dengan Filler Abu Sawit - Carbon Black. J FTEKNIK ., 1 (2) : 1 – 13.
Nakason, C.,Saiwari, S. dan Kaesaman, A. 2006. Thermoplastic Vulcanizates Based on Maleated Natural Rubber/Polypropylene Blends: Effect of Blend Ratios on Rheological, Mechanical, and Morphological Properties. Polymer Engineering and Science, 46,594-600.
Nelson. P. and Kutty. S.K.N. 2004. Effect of Silane Coupling Agent on Cure Characteristics and Mechanical Properties of Nitrile Rubber/Reclaimed Rubber Blend Progres in Rubber, Plastics and Recyling Technology. 20(3) : 213-228.
Padhiyar. S, Desai. R. 2011. Silane Coupling Agent Work as Crosslinking Agent in Elastomer. International Journal of Engineering, Economics and Management. 2 : 14 – 17.
Padhiyar. S, Shah. D. 2013. Effect of silanes as crosslinking agent with the NBR rubber. International Journal of Innovative Research in Science, Engineering and Technology. 2(5) : 1577 – 1581.
Pongdong. W, Nakason. C, Kummerlöwe. C, and Vennemann. N. Influence of Filler from a Renewable Resource and Silane Coupling Agent on the Properties of Epoxidized Natural Rubber Vulcanizates. Journal of Chemistry. 15 : 1 -15.
Saowapark, T. 2005. Reinforcement of Natural Rubber with Silica/Carbon Black Hybrid Filler, Thesis, Mahidol University.
Turmanova, S, Genieva. S & Vlaev. L, Zlatarov. A. 2012. Obtaining Some Polymer Composites Filled with Rice Husks Ash-A Review. International Journal of Chemistry. 4(4) : 62 – 89.
Vichitcholchai N., Na-Ranong N., Noisuwan W., and Arayapranee W. 2012. Using Rice Husk Ash as Filler in Rubber Industry. Rubber Thai Journal, 1: 48-55.
Wang, M. J., P. Zhang., dan K. Mahmud., 2001. Carbon-Silica Dual Phase Filler, A New Generation Reinforcing Agent For Rubber. Rubber Chemistry and Technology, 74 (1), 124-128.
DOI: http://dx.doi.org/10.28959/jdpi.v28i1.2334
Refbacks
- There are currently no refbacks.
Copyright (c) 2017 Jurnal Dinamika Penelitian Industri

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.