The Effect of Filler Substitution on the Mechanical Properties and Morphology of CR/NR Composite

hesty eka mayasari, agung yanuar wirapraja

Abstract


Filler is one of the most important additives in making rubber goods. Filler can improve the properties of rubber goods. This study aims to determine the effect of filler substitution on the chloroprene/natural rubber (CR/NR) composite. The filler used in this study are carbon black (CB) N330, combination of zeolite and CB (1:1), combination of kaolinite and CB (1:1), and combination of bentonite and CB (1:1). The composites were done by a two-roll mill and hydraulic press. The mechanical properties and the morphology of CR/NR composite were studied using tensile strength tester and scanning electron microscope. The elemental composition of the composite was studied by X-ray fluorescence. From the study, it is known that the carbon black as a single filler gives the highest tensile strength and tear strength. The zeolite as substitute filler gives the highest tensile strength and elongation. The bentonite as substitute filler gives the lowest tensile strength and tear strength. All of the composites show fine dispersion in SEM micrograph. Zeolite as substitute filler is a potential alternative filler for CR/NR composite

Full Text:

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References


K. Ahmed, S. Nizami, N. Z. Raza, and K. Shirin, “Cure Characteristics , Mechanical and Swelling Properties of Marble Sludge Filled EPDM Modified Chloroprene Rubber Blends,” Adv. Mater. Phys. Chem., vol. 2012, no. June, pp. 90–97, 2012.

T. Siriyong and W. Keawwattana, “Utilization of different curing systems and natural zeolite as filler and absorbent for natural rubber/Nitrile rubber blend,” Kasetsart J. - Nat. Sci., vol. 46, no. 6, pp. 918–930, 2012.

H. Ismail and M. Mathialagan, “Comparative study on the effect of partial replacement of silica or calcium carbonate by bentonite on the properties of EPDM composites,” Polym. Test., vol. 31, no. 2, pp. 199–208, 2012.

N. Kongvasana, A. Kositchaiyong, E. Wimolmala, C. Sirisinha, and N. Sombatsompop, “Fly ash particles and precipitated silica as fillers in NR/CR vulcanizates under thermal and thermal-oil ageing,” Polym. Adv. Technol., vol. 22, no. 6, pp. 1014–1023, 2011.

B. B. Pajarito, K. A. Gines, A. S. Baluyut, J. A. A. de Leon, and R. P. Villa, “Effect of Replacing Carbon Black with Organo-Modified Bentonite and Acid-Activated Zeolite on Vulcanization Characteristics of Natural Rubber Tire Tread,” Mater. Sci. Forum, vol. 890, pp. 59–63, 2017.

Y. Zhang, Q. Liu, S. Zhang, Y. Zhang, Y. Zhang, and P. Liang, “Applied Clay Science Characterization of kaolinite / styrene butadiene rubber composite : Mechanical properties and thermal stability,” Appl. Clay Sci., vol. 124–125, pp. 167–174, 2016.

F. A. N. Azar and M. Sen, “Effects of accelerator type on stress relaxation behavior and network structure of aged natural rubber/chloroprene rubber vulcanizates,” J. Elastomers Plast., vol. 49, no. 5, pp. 381–396, 2017.

B. P. Kapgate and C. Das, “Reinforcing efficiency and compatibilizing effect of sol-gel derived in situ silica for natural rubber/chloroprene rubber blends,” RSC Adv., vol. 4, no. 102, pp. 58816–58825, 2014.

H. E. Mayasari and Y. A. Wirapraja, “Pengaruh Jenis Bahan Pengisi Terhadap Karakteristik Pematangan Kompon Kloroprena/Karet Alam,” J. Teknol. Proses dan Inov. Ind., vol. 1, no. 4, 2019.

N. N. Petrova, J. Lee, V. V. Portnyagina, D. Y. Jeong, and J. H. Cho, “Antiswelling and frost-resistant properties of a Zeolite-modified rubber mechanical seal at low temperature,” Bull. Korean Chem. Soc., vol. 36, no. 2, pp. 464–467, 2015.

H. Nabil, H. Ismail, and A. R. Azura, “Compounding, mechanical and morphological properties of carbon-black-filled natural rubber/recycled ethylene-propylene-diene-monomer (NR/R-EPDM) blends,” Polym. Test., vol. 32, no. 2, pp. 385–393, 2013.

H. Hassankhani, H. Atashi, and D. Mohebbi, “Reducing of heat loss of rubber compound using natural zeolite filler : effect of partially substitution of fillers on compound properties,” Iran. Polym. J., vol. 0, no. 0, p. 0, 2018.

I. Abed, M. Paraschiv, K. Loubar, F. Zagrouba, and M. Tazerout, “Thermogravimetric investigation and thermal conversion kinetics of typical North African and middle eastern lignocellulosic wastes,” BioResources, vol. 7, no. 1, pp. 1200–1220, 2012.




DOI: http://dx.doi.org/10.36048/jtpii.v6i2.7380

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